dihydroxyacetone

Three steps

• 4,8-dimethylnonanoyl-CoAReach from here →
  1. Glycerone phosphate phosphohydrolase
  2. glyceronephosphate O-acyltransferase (DHAP)
  3. Carnitine Dimethyl Nonanoyl Transferase, Revsible, Peroxisomal

  Catalysed by ALPL, ALPP, ALPI, ALPG and 3 moreextracellular space, peroxisomeOne of 3 routes

• tetradecanedioyl-CoAReach from here →
  1. Glycerone phosphate phosphohydrolase
  2. glyceronephosphate O-acyltransferase (DHAP)
  3. Fatty Acid Beta Oxidation (C16Dc->C14Dc), Peroxisomal

  Catalysed by ALPL, ALPP, ALPI, ALPG and 5 moreextracellular space, peroxisome

• hexadecanedioyl-CoAReach from here →
  1. Glycerone phosphate phosphohydrolase
  2. glyceronephosphate O-acyltransferase (DHAP)
  3. Production of Hexadecanedioylcarnitine

  Catalysed by ALPL, ALPP, ALPI, ALPG and 4 moreextracellular space, peroxisome, cytosolOne of 2 routes

• pristanoyl-CoAReach from here →
  1. Glycerone phosphate phosphohydrolase
  2. glyceronephosphate O-acyltransferase (DHAP)
  3. fatty-acid-CoA ligase

  Catalysed by ALPL, ALPP, ALPI, ALPG and 2 moreextracellular space, peroxisome, cytosolOne of 2 routes

• 1-O-hexadecylglycerone 3-phosphateReach from here →
  1. Glycerone phosphate phosphohydrolase
  2. glyceronephosphate O-acyltransferase (DHAP)
  3. 1-hexadecanoylglycerone 3-phosphate + hexadecan-1-ol = 1-O-hexadecylglycerone 3-phosphate + hexadecanoate + H(+)

  Catalysed by ALPL, ALPP, ALPI, ALPG and 2 moreextracellular space, peroxisome

• undecanoyl-CoAReach from here →
  1. Glycerone phosphate phosphohydrolase
  2. glyceronephosphate O-acyltransferase (DHAP)
  3. medium-chain acyl-CoA ligase (undecylic acid)

  Catalysed by ALPL, ALPP, ALPI, ALPG and 7 moreextracellular space, peroxisome, cytosolOne of 3 routes

• hexadecanoateReach from here →
  1. Glycerone phosphate phosphohydrolase
  2. glyceronephosphate O-acyltransferase (DHAP)
  3. 1-hexadecanoylglycerone 3-phosphate + hexadecan-1-ol = 1-O-hexadecylglycerone 3-phosphate + hexadecanoate + H(+)

  Catalysed by ALPL, ALPP, ALPI, ALPG and 2 moreextracellular space, peroxisomeOne of 2 routes

• (5Z)-tetradecenoyl-CoAReach from here →
  1. Glycerone phosphate phosphohydrolase
  2. glyceronephosphate O-acyltransferase (DHAP)
  3. long-chain-fatty-acid-CoA ligase (physeteric acid)

  Catalysed by ALPL, ALPP, ALPI, ALPG and 9 moreextracellular space, peroxisome, cytosolOne of 8 routes

• (3E)-decenoyl-CoAReach from here →
  1. Glycerone phosphate phosphohydrolase
  2. glyceronephosphate O-acyltransferase (DHAP)
  3. Fatty Acid Beta Oxidation (C12:1->C10:1), Mitochondrial

  Catalysed by ALPL, ALPP, ALPI, ALPG and 5 moreextracellular space, peroxisome, mitochondrial matrix

• (2R,6)-dimethylheptanoyl-CoAReach from here →
  1. Glycerone phosphate phosphohydrolase
  2. glyceronephosphate O-acyltransferase (DHAP)
  3. acetyl-CoA C-acyltransferase (3-oxo-4(R),8-dimethyl-nonanoyl-CoA)

  Catalysed by ALPL, ALPP, ALPI, ALPG and 4 moreextracellular space, peroxisome, mitochondrial matrix

• (7Z)-hexadecenoyl-CoAReach from here →
  1. Glycerone phosphate phosphohydrolase
  2. glyceronephosphate O-acyltransferase (DHAP)
  3. long-chain-fatty-acid-CoA ligase (7-palmitoleic acid)

  Catalysed by ALPL, ALPP, ALPI, ALPG and 9 moreextracellular space, peroxisome, cytosolOne of 8 routes

• tricosanoyl-CoAReach from here →
  1. Glycerone phosphate phosphohydrolase
  2. glyceronephosphate O-acyltransferase (DHAP)
  3. long-chain-fatty-acid-CoA ligase (tricosanoic acid)

  Catalysed by ALPL, ALPP, ALPI, ALPG and 9 moreextracellular space, peroxisome, cytosolOne of 4 routes