Compound
(13R)-S-glutathionyl-(14S)-hydroxy-(4Z,7Z,9E,11E,16Z,19Z)-docosahexaenoate
A docosanoid anion obtained by deprotonation of the three carboxy groups and protonation of the glutamyl alpha -amino group of (13R)-S-glutathionyl-(14S )-hydroxy-(4Z,7Z,9E,11E,16 Z,19Z )-docosahexaenoic acid; major species at pH 7.3.
Definition from ChEBI (CHEBI:137407), read 2026-09-23. CC BY 4.0.
Structure
No three-dimensional record for this entry.
- Class
- Organic compound, anion
- Formula
- C32H45N3O9S
- Mass
- 647.791 g/mol
- Charge
- -2
- InChIKey
- NWYKIASJHFGEAN-CPMAONNBSA-L
- SMILES
- CC/C=CC/C=CC[C@H](O)[C@@H](/C=C/C=C/C=CC/C=CCCC(=O)[O-])SC[C@H](NC(=O)CC[C@H]([NH3+])C(=O)[O-])C(=O)NCC(=O)[O-]
- Look it up
- ChEBIBy InChIKey
Identity from ChEBI. Not evidence.
What it touches on the way
Mechanistic reach
2 entities
2 entities reached.
0 reported hops2 assembled from the scaffold
What the reference databases state
Statements
2 statements
2 statements · 1 reference database · Subject: (13R)-S-glutathionyl-(14S)-hydroxy-(4Z,7Z,9E,11E,16Z,19Z)-docosahexaenoate · Sources: Rhea
- (13R)-S-glutathionyl-(14S)-hydroxy-(4Z,7Z,9E,11E,16Z,19Z)-docosahexaenoate is metabolised by GSTM4ProteinRhea RHEA:53508Inferred only
- (13R)-S-glutathionyl-(14S)-hydroxy-(4Z,7Z,9E,11E,16Z,19Z)-docosahexaenoate is a substrate of LTC4SProteinRhea RHEA:53508Inferred only
Reactions
2 reactions
(13S,14S)-epoxy-(4Z,7Z,9E,11E,16Z,19Z)-docosahexaenoate+glutathione(13R)-S-glutathionyl-(14S)-hydroxy-(4Z,7Z,9E,11E,16Z,19Z)-docosahexaenoate
Reaction pageLeft to rightBalance undeterminable
Rhea RHEA:53508CC BY 4.0Reference data
(13R)-S-glutathionyl-(14S)-hydroxy-(4Z,7Z,9E,11E,16Z,19Z)-docosahexaenoate+waterCHEBI:137408+L-glutamate(1-)
Catalysed by GGT1
Reaction pageLeft to rightBalance undeterminable
Rhea RHEA:53512CC BY 4.0Reference data
Other names
4 names
Resolves to: (13R)-S-glutathionyl-(14S)-hydroxy-(4Z,7Z,9E,11E,16Z,19Z)-docosahexaenoate
- Also called
- MCTR1(2-)MCTR1(2−)
- Systematic name
- (4Z,7Z,9E,11E,13R,14S,16 Z,19Z )-13-({(2R)-2-{[(4S)-4-azaniumyl-4-carboxylatobutanoyl]amino}-3-[(carboxylatomethyl)amino]-3-oxopropyl}sulfanyl)-14-hydroxydocosa-4,7,9,11,16,19-hexaenoate(4Z,7Z,9E,11E,13R,14S,16Z,19Z)-13-({(2R)-2-{[(4S)-4-azaniumyl-4-carboxylatobutanoyl]amino}-3-[(carboxylatomethyl)amino]-3-oxopropyl}sulfanyl)-14-hydroxydocosa-4,7,9,11,16,19-hexaenoate